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烯烃复分解反应：理论与实践 Olefin Metathesis: Theory And Practice
基本信息
Format:Hardback 608 pages
Publisher:John Wiley & Sons Inc
Imprint:John Wiley & Sons Inc
ISBN:9781118207949
Published:23 May 2014
Weight:1778g
Dimensions:288 x 217 x 39 (mm)
信息仅供参考，具体请以到手的实物为准
书籍简介●
这是对现代烯烃复分解的理论和方法的完整检验，现代烯烃复分解是研究和工业中使用广泛的化学反应之一。
为非专业人士提供基本信息，同时也向专家解释该领域的新趋势和进展
●讨论各种类型的复分解反应，包括 CM、RCM、烯炔复分解、ROMP 和串联过程，以及它们的常见应用
●概述了行业工具——从重要的活性金属配合物类别到反应条件——并为常见反应问题提出了实用的解决方案
●包括商业催化剂结构表以及对商业催化剂供应商的建议
This is a complete examination of the theory and methods of modern olefin metathesis, one of the most widely used chemical reactions in research and industry.
Provides basic information for non-specialists, while also explaining the latest trends and advancements in the field to experts
Discusses the various types of metathesis reactions, including CM, RCM, enyne metathesis, ROMP, and tandem processes, as well as their common applications
Outlines the tools of the trade—from the important classes of active metal complexes to optimal reaction conditions—and suggests practical solutions for common reaction problems
Includes tables with structures of commercial catalysts, and recommendations for commercial catalyst suppliers
作者简介
KAROL GRELA，波兰科学院有机化学研究所教授，波兰华沙大学化学系生物化学研究中心有机金属合成实验室主任。 他撰写了 100 多篇同行评审论文，是欧洲期刊 Chemistry 的编辑委员会成员以及欧洲有机化学和有机金属学期刊的顾问委员会成员。
KAROL GRELA is a Professor at the Institute of Organic Chemistry, Polish Academy of Sciences, and the Director of the Organometallic Synthesis Laboratory at the Biological and Chemical Research Centre of the Faculty of Chemistry, University of Warsaw, Poland. Having written over 100 peer-reviewed papers, he is on the editorial board of Chemistry—a European Journal and on the advisory board for the European Journal of Organic Chemistry and Organometallics.
目录
部分目录，仅供参考
PREFACE ix
CONTRIBUTORS xi
PART I APPLICATIONS OF OLEFIN METATHESIS REACTIONS 1
Section I INTRODUCTION 3
1 Olefin Metathesis Reactions: From a Historical Account to Recent Trends 5
Didier Astruc
Section II TYPES OF OLEFIN METATHESIS REACTIONS 37
2 Cross Metathesis 39
Karolina ? Zukowska and Karol Grela
3 Ring-Closing Metathesis 85
Bianca J. van Lierop, Justin A. M. Lummiss, and Deryn E. Fogg
4 Ene-Yne Metathesis 153
Steven T. Diver and Justin R. Griffiths
5 Domino and Other Olefin Metathesis Reaction Sequences 187
Bernd Schmidt and Stefan Krehl
6 Enantioselective Olefin Metathesis 233
Brice Stenne and Shawn K. Collins
7 Olefin Metathesis Polymerization 269
Astrid-Caroline Knall and Christian Slugovc
Section III APPLICATIONS OF OLEFIN METATHESIS REACTIONS 285
8 Applications in the Synthesis of Natural and Biologically Active Molecules 287
Janine Cossy
9 Multifold Ring-Closing Olefin Metatheses in Syntheses of Organometallic Molecules with Unusual Connectivities 311
Tobias Fiedler and John A. Gladysz
10 Industrial Applications of Olefin Metathesis Polymerization 329
Christian Slugovc
11 Commercial Potential of Olefin Metathesis of Renewable Feedstocks 335
Andrew Nickel and Richard L. Pederson
12 Challenges and Opportunities for Scaling the Ring-Closing Metathesis Reaction in the Pharmaceutical Industry 349
Keith R. Fandrick, Jolaine Savoie, Nathan Yee, Jinhua J. Song, and Chris H. Senanayake
PART II DEVELOPMENT OF THE TOOLS 367
Section IV DIFFERENT CLASSES OF OLEFIN METATHESIS CATALYSTS 369
13 Well-Defined Olefin Metathesis Catalysts Based on Metals of Group 4–7 371
Cezary Pietraszuk
14 Ruthenium-Benzylidene Olefin Metathesis Catalysts 397
Georgios C. Vougioukalakis
15 Ruthenium-Indenylidene and Other Alkylidene Containing Olefin Metathesis Catalysts 417
César A. Urbina-Blanco, Stefano Guidone, Steven P. Nolan, and Catherine S. J. Cazin
16 Hoveyda-Type Olefin Metathesis Complexes 437
Yakov Ginzburg and N. Gabriel Lemcoff
17 Schiff Base Catalysts and Other Related Latent Systems for Polymerization Reactions 453
Yohann Morin and Régis M. Gauvin
Section V DEVELOPMENT OF CONCEPTS IN OLEFIN METATHESIS CATALYSTS 473
18 Novel Concepts in Catalyst Design—a Case Study of Development of Hoveyda-Type Complexes 475
Micha? Barbasiewicz
19 Theoretical Attempts: “In Silico Olefin Metathesis”—How Can Computers Help in the Understanding of Metathesis Mechanisms and in Catalysts Development? 483
Albert Poater, Laura Falivene, and Luigi Cavallo
20 Immobilization of Olefin Metathesis Catalysts 495
Michael R. Buchmeiser
21 Olefin Metathesis inWater and Aqueous Media 515
Bruce H. Lipshutz and Subir Ghorai
22 Olefin Metathesis in Green Organic Solvents and Without Solvent 523
